Ninki Cosplayer no Ane o Choukyou Haishin Shite Mita

A little brother living together with his big sister is distraught when he finds out
his cosplaying big sister has been propositioned by a famous cameraman.
Afraid that she'll be stolen away from him, he decides to do some filming of his own,
and sexually train her via live-stream. He binds her up, and gets to work...

[From DLsite English]